2023年度

• ①YUi Okuda, Eiichi Kido, Ken Hirota, and Tadashi Mizutani
  "Water-Resistant Tough Composites of Cellulose Nanofibers and Hydroxyapatite ”
  ACS Applied Polymer Materials 2023 XXX-XXX 公開ページ

2022年度

• ①Kazuki Shimada, Tadashi Mizutani
  "Synthesis and reactivity of10,15,20-triaryl-5-oxaporphyrin copper complexes ”
  Tetrahedron Letters 2022, 3, 153977 公開ページ


• ②YUi Okuda, Ryosuke Shigemasa, Ken Hirota, and Tadashi Mizutani
  "In Situ Crystallization of Hydroxyapatite on Carboxymethyl Cellulose as a Biomimetic Approach to Biomass-Derived Composite Materials"
  ACS Omega 2022,７,14,12127-12137 公開ページ

2021年度

• ①YUi Okuda , Tadashi Mizutani*, Ken Hirota, Takayuki Hayashi, and Kazuhito Zinno
  "Nonbrittle Nanocomposite Materials Prepared by Coprecipitation of TEMPO-Oxidized Cellulose Nanofibers and Hydroxyapatite”
  ACS Sustainable Chem. Eng. 2021, 9, 158-167 公開ページ


• ②Kazuhisa Kakeya, Hiroyuki Fukagawa, Akihiro Teraoka, and Tadashi Mizutani
  "Ring Closure Reaction of 19-Substituted Bilinones to 5-Oxaporphyrin Metal Complexes Induced　by Zn2+ and Cu2+ －Application to Turn-on Red Fluorogenic Probes for Zinc Ions－”
  CSJ Journals Chem. Lett. 2021, 50, 908-911 公開ページ

2019年度

• ① YUi Okuda; Ken Hirota; Tadashi Mizutani; Yasuhiro Aoyama.
  "Co-precipitation of tapioca starch and hydroxyapatite. Effects ofphosphorylation of starch on mechanical properties of the composites”
  Results in materials 2019, 3,100035 公開ページ

2018年度

• ① Shirai,Kaho; Takagi,Akuto; Taniwaki,Ryosuke; Kurata,Masanori; Kinugasa,Kentaro; Yamamoto,Koji; Tadashi,Mizutani; Takao,Yuko; Moriwaki,Kazuyuki; Ito,Takatoshi; Iwai,Toshiyuki; Matsumoto,Fukashi; Ohno,Toshinobu.
  "Synthesis of chloroboron(Ⅲ) 3,4,12,13,21,22-hexabromosubnaphthalocyanine under high dilution conditions and comparative studies of effects of halogenation on physicochemical properties of subnaphthalocyanines”
  Tetrahedron 2018,74,4220-4225 公開ページ

2017年度

• ① Takagi,Akuto;Mizutani,Tadashi
  ."Control of the molecular packing of chloroboron(Ⅲ) and fluoroboron(Ⅲ) subnaphthalocyanines by designing peripheral substituents”
  RSC Adv. 2017,7,54235-54245 公開ページ
  


• ② Kusakabe,Akane;Hirota,Ken;Mizutani,Tadashi.
  "Crystallisation of hydroxyapatite in phosphorylated poly(vinyl alcohol) as a synthetic route to tough mechanical hybrid materials”
  Materials Science and Engineering: C 2017,70,487-493 公開ページ

2016年度

• ① Takagi,Akuto;Mizutani,Tadashi.
  "p-n interface stabilization of planar heterojunction organic photovoltaics by an ethyleneoxy side chain of methanofullerenes”
  Synthetic Metals 2016,215,223-228 公開ページ
  


• ②Yamamoto,koji;Takagi,Akuto;Hada,Miyako;Taniwaki,Ryosuke;Mizutani,Tadashi.
  "Synthesis and optoelectronic properties of hexachloro- and hexaiodosubnaphthalocyanines as organic electronic materials”
  Tetrahedron 2016,72,4918-4924 公開ページ


• ③ Tadashi Mizutani
  "Coupled oxidation of iron tetraarylporphyrins as a synthetic tool for linear tetrapyrroles”
  Journal of Porphyrins and Phthalocyanines 2016, 20, 108-116 公開ページ

2015年度以前

2015年. ① Kazuhisa Kakeya; Atsuko Shimizu; Kenta Akasaka; Tadashi Mizutani. "Substituent effects on selectivity of coupled oxidation of iron tetraphenylporphyrins” Journal of Porphyrins and Phthalocyanines 2015 726-733 公開ページ
② Fujimoto,Takahiro;Furuta,Nao;Mizutani,Tadashi. "Kinetics of reactions at an interface: functionalisation of silicate glass with porphyrins via covalent bonds” Org. Biomol. Chem 2015,13,3371-3377 公開ページ

2014年. ① Takao,Yuko;Masuoka,Tomoaki;Yamamoto,Koji;Mizutani,tadashi. "Synthesis and properties of novel fluorinated subnaphthalocyanines for organic photovoltaic cells” Tetrahedron Letters 2014,55(33),4564-4567
② Furuta,Nao;Yagi,takaaki;Mizutani,tadashi. "Kinetics and mechanisms of hydrolysis of tetraphenylporphyrins tethered to silicate glass via a primary or tertiary alcohol linker” Tetrahedron 2014,70,4336-4342
③ Kakeya, Kazuhisa; Aozasa, Masakatsu; Mizutani, Tadashi. “Nucleophilic Ring-opening of meso-Substituted 5-Oxaporphyrin by Oxygen, Nitrogen, Sulfur, and Carbon Nucleophiles” The Journal of Organic Chemistry 2014, 79 (6) , 2591-2600
④ Furuta, Nao; Mizutani, Tadashi. “Tris(3-hydroxypropyl)methyl as a stable linker for porphyrin monolayer on silicate glass” Thin Solid Films 2014,556,174-185.
⑤ Sandell, Jonas P. L.; Kakeya, Kazuhisa; Mizutani, Tadashi. “Ring-opening with One Dioxygen Molecule in the Coupled Oxidation of IronTetraarylporphyrins” Tetrahedron Letters 2014, 55(9), 1532-1535.

2012年. ① Kakeya, Kazuhisa; Nakagawa, Aya; Mizutani, Tadashi; Hitomi, Yutaka; Kodera, Masahito. “Synthesis, Reactivity, and Spectroscopic Properties of meso-Triaryl-5-oxaporphyrins” The Journal of Organic Chemistry 2012, 77, 6510-6519.

2011年. ① Tsuji, Tomohiro; Gonda, Katsuya; Aoyama, Yasuhiro; Tokunaga, Takeshi; Sando, Shinsuke. “Inhibitor-substituted Boron-dipyrromethene as a Turn-on Fluorescence Probe for Enzymes ” Chemistry Letters 2011, 40, 1275-1277.
② Nakamura, Ryosuke; Kakeya, Kazuhisa; Furuta, Nao; Muta, Etsuko; Nishisaka, Hiroaki; Mizutani, Tadashi. “Synthesis of para- or ortho-Substituted Triarylbilindiones and Tetraarylbiladienones by Coupled Oxidation of Tetraarylporphyrins ” The Journal of Organic Chemistry 2011, 76, 6108-6115.
③ Minamizima, Nagisa; Furuta, Nao; Wakunami, Shintaro; Mizutani, Tadashi. “Functionalization of Silica Surface by Tetrahydroxyporphyrin via Si-O Linkages” Bulletin of the Chemical Society of Japan 2011, 7, 794-801.
④ Furuta, Nao; Mizutani, Tadashi. “Solvatochromism of triarylbilindiones: far-red-absorbing bilindiones formed in aprotic amides and amines” Supramolecular Chemistry 2011, 23(1-2), 74-82.

2010年. ① Matsumoto, Sayaka; Iwamoto, Hiroya; Mizutani, Tadashi. “Water Accessibility to the Binding Cleft as a Major Switching Factor from Entropy-Driven to Enthalpy-Driven Binding of an Alkyl Group by Synthetic Receptors” Chemistry-An Asian Journal 2010, 5(5), 1163-1170.

2009年. ① Mizutani, Tadashi; Nemoto, Shohei; Yoshida, Masasuke; Watanabe, Yo-hei. “Temperature-dependent regulation of Thermus thermophilus DnaK/DnaJ chaperones by DafA protein”, Genes to Cells 2009, 14(12), 1405-1413.
② Murakami, Ryosuke; Minami, Asuka; Mizutani, Tadashi “Molecular recognition in anisotropic media. Binding of alkylpyridines to amphiphilic zinc porphyrins incorporated in liposomal bilayer membranes” Organic & Biomolecular Chemistry 2009, 7(7), 1437-1444.
③ Akasaka, Hiroaki; Yukutake, Hajime; Nagata, Yuko; Funabiki, Takuzo; Mizutani, Tadashi; Takagi, Hideki; Fukushima, Yoshiaki; Juneja, Lekh Raj; Nanbu, Hironobu; Kitahata, Kouichi. “Selective adsorption of biladien-ab-one and zinc biladien-ab-one to mesoporous silica” Microporous and Mesoporous Materials 2009 331-338.
④ Shimizu, Tomofumi; Asano, Naomi; Mizutani, Tadashi; Chang, Ho-Chol; Kitagawa, Susumu. “Allosteric binding of amino alcohols and diamines by dimeric zinc biladienone” Tetrahedron Letters 2009, 50(5), 536-539.

2008年. ① Yagi, Shigeyuki; Hamakubo, Katsushi; Ikawa, Shigeru; Nakazumi, Hiroyuki; Mizutani, Tadashi. “Homohelicity-enriched zinc bilinone dimers with chiral aliphatic spacers. Synthesis and application to chiral induction of a nematic liquid crystal” Tetrahedron 2008, 64(46),

2007年. ① Iwamoto, Hiroya; Mizutani, Tadashi; Kano, Koji. “Thermodynamics of hydrophobic interactions: entropic recognition of a hydrophobic moiety by poly(ethylene oxide)-zinc porphyrin conjugates” Chemistry--An Asian Journal 2007, 2(10), 1267-1275.
② Asano, Naomi; Uemura, Sayo; Kinugawa, Tomoya; Akasaka, Hiroaki; Mizutani, Tadashi. “Synthesis of Biladienone and Bilatrienone by Coupled Oxidation of Tetraarylporphyrins” Journal of Organic Chemistry 2007, 72(14), 5320-5326.

2006年. ① Matsui, Eriko; Matsuzawa, Nobuyuki N.; Harnack, Oliver; Yamauchi, Takae; Hatazawa, Tsuyonobu; Yasuda, Akio; Mizutani, Tadashi. “A new molecular switch based on helical biladienone” Advanced Materials (Weinheim, Germany) 2006, 18(19), 2523-2528.
② Kotomari, Satoshi; Yoshikawa, Tsukasa; Mizutani, Tadashi; Takagi, Hideki. “N-methylporphyrin as a binding motif for the recognition of a phenolic hydroxy group” Chemistry Letters 2006, 35(9), 1020-1021.
③ Hamakubo, Katsushi; Yagi, Shigeyuki; Nakazumi, Hiroyuki; Mizutani, Tadashi; Kitagawa, Susumu. “Homohelicity induction of propylene-linked zinc bilinone dimers by complexation with chiral amine and ? -amino esters. Preorganization of structurally coupled homohelical subunits” Tetrahedron 2006, 62(15), 3619-3628.
④ Kita, Kojiro; Tokuoka, Taiyo; Monno, Eriko; Yagi, Shigeyuki; Nakazumi, Hiroyuki; Mizutani, Tadashi. “Thermochromic and solvatochromic zinc biladienones: dynamic equilibria of a metal complex having a flexible framework sensitive to environment” Tetrahedron Letters 2006, 47(10), 1533-1536.

2005年. ① Hamakubo, Katsushi; Hama, Shimpei; Yagi, Shigeyuki; Nakazumi, Hiroyuki; Mizutani, Tadashi. “Extraordinary doping effects of chiral helical linear tetrapyrrole-Zn(II) complexes on chiral nematic induction of MBBA liquid crystal” Chemistry Letters 2005, 34(10), 1454-1455.
② Hamakubo, Katsushi; Yagi, Shigeyuki; Nakazumi, Hiroyuki; Mizutani, Tadashi; Kitagawa, Susumu. “Synchronous helicity control in zinc bilinone trimer” Tetrahedron Letters 2005, 46(42), 7151-7154.
③ Takagi, Hideki; Mizutani, Tadashi; Horiguchi, Takuya; Kitagawa, Susumu; Ogoshi, Hisanobu. “Efficient axial chirality induction in biphenyldiol triggered by proton-transferred hydrogen bonding with chiral amine” Organic & Biomolecular Chemistry 2005, 3(11), 2091-2094.
④ Yamauchi, Takae; Mizutani, Tadashi; Wada, Kenji; Horii, Shoji; Furukawa, Hirotaka; Masaoka, Shigeyuki; Chang, Ho-Chol; Kitagawa, Susumu. “A facile and versatile preparation of bilindiones and biladienones from tetraarylporphyrins” Chemical Communications (Cambridge, United Kingdom) 2005, (10), 1309-1311.

2003年. ① Mizutani, Tadashi; Kozake, Katsuyuki; Wada, Kenji; Kitagawa, Susumu, “An Efficient Recognition Motif for an Alkyl Moiety in Water” Chem. Commun. 2003, (23), 2918-2919.
② Wada, Kenji; Mizutani, Tadashi; Kitagawa, Susumu, “Synthesis of Functionalized Porphyrins as Oxygen Ligand Receptors” J. Org. Chem. 2003, 68(13), 5123-5131.
③ Wada, Kenji; Mizutani, Tadashi; Matsuoka, Hideki; Kitagawa, Susumu “A New Strategy for the Design of Water-Soluble Synthetic Receptors: Specific Recognition of DNA Intercalators and Diamines” Chem. Eur. J. 2003, 9(10), 2368-2380.

2002年. ① Kurahashi, T.; Mizutani, T.; Yoshida, J. “Functionalized DMAP catalysts for regioselective acetylation of carbohydrates” Tetrahedron, 2002, 58(43), 8669-8677.
② Kazuhiro Uemura, Susumu Kitagawa, Mitsuru Kondo, Koichi Fukui, Ryo Kitaura, Ho-Chol Chang, and Tadashi Mizutani “Novel Flexible Frameworks of Porous Cobalt(II) Coordination Polymers That Show Selective Guest Adsorption Based on the Switching of Hydrogen-Bond Pairs of Amide Groups” Chem. Eur. J. 2002, 8 (16), 3586-3600.
③ Mizutani, T.; Wada, K.; Kitagawa, S. “Hydrophobic Environment of Gable-type Bisporphyrin Receptors in Water Promotes Binding of Amines and Oligopeptides” Chem. Commun. 2002, (15), 1626-1627.
④ Hayashi, T.; Aya, T.; Nonoguchi, M.; Mizutani, T.; Hisaeda, Y.; Kitagawa, S.; Ogoshi, H. “Chiral recognition and chiral sensing using zinc porphyrin dimers” Tetrahedron, 2002, 58(14), 2803-2811.

2001年. ① Shigeyuki Masaoka, Shuhei Furukawa, Ho-Chol Chang, Tadashi Mizutani, Susumu Kitagawa “A New Class of Cyclic Hexamer: [Co₆L₆]^24- (H₆L=hexaazatriphenylene hexacarboxylic acid)” Angew. Chem. Int. Ed. 2001, 40(20), 3817-3819.
② Mizutani, T.; Wada, K.; Kitagawa, S. “Molecular Recognition of DNA Intercalators at Nanomolar Concentration in Water” J. Am. Chem. Soc. 2001, 123(26), 6459-6460.
③ Yagi, S.; Morinaga, T.; Nomura, T.; Takagishi, T.; Mizutani, T.; Kitagawa, S.; Ogoshi, H. “Solvent Effects on Helicity Induction of Zinc Bilinone Bearing a Chiral Auxiliary at the Helix Terminal”. J. Org. Chem. 2001, 66(11), 3848-3853.
④ Hitomi, Y.; Hayashi, T.; Wada, K.; Mizutani, T.; Hisaeda, Y.; Ogoshi, H. “Interprotein Electron Transfer Reaction Regulated by an Artificial Interface” Angew. Chem. Int. Ed. Engl. 2001, 40 (6), 1098-1101.

2000年. ① Mizutani, T.; Sakai, N.; Yagi, S.; Takagishi, T.; Kitagawa, S.; Ogoshi, H. “Allosteric Chirality Amplification in Zinc Bilinone Dimer”. J. Am. Chem. Soc. 2000, 122 (4), 748-749.
総説など Mizutani, T. “Development of tough hybrid materials by regulated crystallization of hydroxyapatite inspired by bone formation” Impact, Volume 2020, Number 1, February 2020, pp. 27-29(3).
Mizutani, T.; Yagi, S. “Linear tetrapyrroles as functional pigments in chemistry and biology” J. Porphyrins and Phthalocyanines, 2004, in press.
Mizutani, T. “Design and Mechanism of Molecular Recognition of Water-soluble Synthetic Receptors” J. Synth. Org. Chem .2001, 59(12), 1170-1180.