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Kodera and Hitomi Research Group

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PUBLICATIONS

Publications (since 2008)

2017

3.

Natsumi Ohashi, Akiko Nomura, Masahito Kodera, and Yutaka Hitomi*
Structurally Simple Cell-permeable Porphyrins: Efficient Cellular Uptake and Photo-toxicity of Porphyrins with Four Peripheral Primary-amine-terminated Oligo(ethylene oxide) Chains

Chemistry Letters, 2017, accepted

2.

Tomokazu Tsuji, Antonius Andre Zaoputra, Yutaka Hitomi, Kaoru Mieda, Takashi Ogura, Yoshihito Shiota, Kazunari Yoshizawa, Hiroyasu Sato, and Masahito Kodera*
Specific Enhancement of Catalytic Activity by a Dicopper Core: Selective Hydroxylation of Benzene to Phenol with Hydrogen Peroxide

Angewandte Chemie International Edition, 2017, 56(27), 7779-7782.
DOI:10.1002/anie.201702291

1.

Akiko Nomura, Yuji Iwamoto, Kengo Arakawa, Akihiro Kashida, Masahito Kodera, and Yutaka Hitomi*
DNA Cleavage through Reductive Dioxygen Activation by Iron-Bleomycin Mimics with Carboxamido Ligation: Correlation between DNA Cleavage Efficacy and Redox Potential

Chemistry Letters, 2017, 46(8), 1109-1111.
DOI:10.1246/cl.170354

2016

3.

Akiko Nomura, Akihiro Kashida, Masahito Kodera, and Yutaka Hitomi*
Cellular Application of Cell-membrane Permeable Fluorescent Zinc Probe Having a Cationic Peptide Tail

Peptide Science 2016, 2017, 173-174.

2.

Prof. Dr. Masahito Kodera,* Shin Ishiga, Tomokazu Tsuji, Katsutoshi Sakurai, Prof. Dr. Yutaka Hitomi, Dr. Yoshihito Shiota, Dr. P. K. Sajith, Prof. Dr. Kazunari Yoshizawa, Dr. Kaoru Mieda and Prof. Dr. Takashi Ogura
"Formation and High Reactivity of the anti-Dioxo Form of High-Spin μ-Oxodioxodiiron(IV) as the Active Species That Cleaves Strong C−H Bonds" (Hot paper)

Chemistry - A European Journal, 2016, 22 (17), 5924-5936.
DOI:10.1002/chem.201600048

1.

Sayuri Okunaka, Hiromasa Tokudome*, Yutaka Hitomi, and Ryu Abe*
"Preparation of Fine Particles of Sheelite-Monoclinic Phase BiVO4 via an Aqueous Chelating Method for Efficient Photocatalytic Oxygen Evolution under Visible-light Irradiation"
Journal of Materials Chemistry A, 2016, 4, 3926-3932.

2015

5.

Akiko Nomura, Natsumi Ohashi, Ryosuke Miyachi, Masahito Kodera and Yutaka Hitomi*
"Effect of central metal ions on the cytotoxicity of metalloporphyrins having a cationic peptide tail"

Peptide Science 2015, 261-264.

4.

Yutaka Hitomi and Kengo Arakawa
"C-O Bond Formation by Arene C-H Activation via Biomimetic and Organocatalytic Oxidation"

in Catalytic Transformations via C-H Activation 2, Science of Synthesis, Ed. by J.-Q. Yu, 2015, pp. 287-313. Georg Thieme Verlag KG, Stuttgart/New York (
LINK)

3.

Yuji Iwamoto, Masahito Kodera, and Yutaka Hitomi*
"Uncaging a Catalytic Hydrogen Peroxide Generator through the Photo-Induced Release of Nitric Oxide from a {MnNO}6 Complex"
Chemical Communications, 2015, 51, 9539-9542.
DOI:
10.1039/C5CC02566D

2.

Yutaka Hitomi*, Yuji Iwamoto, Akihiro Kashida, and Masahito Kodera
"Mononuclear Nonheme Iron(III) Complexes that Show Superoxide Dismutase-like Activity and Antioxidant Effects against Menadione-Mediated Oxidative Stress"
Chemical Communications, 2015, 51, 8702-8704.
DOI:
10.1039/C5CC02019K

1.

Sayuri Okunaka, Hiromasa Tokudome*, Yutaka Hitomi, and Ryu Abe*
"Facile Preparation of Stable Aqueous Titania Sols for Fabrication of Highly Active TiO2 Photocatalyst Films"
Journal of Materials Chemistry A, 2015, 3, 1688-1695.
DOI:
10.1039/C4TA04680C

2014

7.

Yutaka Hitomi,* Kazuki Aoki, Ryosuke Miyachi, Junya Ohyama, Masahito Kodera, Tsunehiro Tanaka, and Fuminori Sugihara
"Gold Nanoparticles Coated with Manganese-Porphyrin that Effectively Shorten the Longitudinal Relaxation Time of Water Molecules Depending on the Particle Size"
Chemistry Letters, 2014, 12, 1901-1903.
DOI:
10.1246/cl.140812

6.

Yutaka Hitomi*, Kengo Arakawa, and Masahito Kodera
"Synthesis, Stability and Reactivity of the First Mononuclear Nonheme Oxoiron(IV) Species with Monoamido Ligation: A Putative Reactive Species Generated from Iron-Bleomycin"
Chemical Communications, 2014, 50 (56), 7485 - 7487.
DOI:
10.1039/C4CC01409J

5.

Yutaka Hitomi*, Toshiyuki Takeyasu, and Masahito Kodera
"Development of Green-Emitting Iron Complex-Based Fluorescent Probes for Intracellular Hydrogen Peroxide Imaging"
Bulletin of the Chemical Society of Japan, 2014, 87(7), 819-824.
DOI:10.1246/bcsj.20140055

4.

Kazuhisa Kakeya, Masakatsu Aozasa, Tadashi Mizutani,* Yutaka Hitomi and Masahito Kodera
"Nucleophilic Ring-opening of meso-Substituted 5-Oxaporphyrin by Oxygen, Nitrogen, Sulfur, and Carbon Nucleophiles"
Journal of Organic Chemistry, 2014, 79 (6), 2591–2600.
DOI: 10.1021/jo5000412

3.

Masahito Kodera*, Tomokazu Tsuji, Tomohiro Yasunaga, Yuka Kawahara, Tomoya Hirano, Yutaka Hitomi, Takashi Nomura, Takashi Ogura, Yoshio Kobayashi, Pookkottu K. Sajith, Yoshihito Shiota and Kazunari Yoshizawa
"Roles of carboxylate donors in O-O bond scission of peroxodiiron(III) to high-spin oxodiiron(IV) with a new carboxylate-containing dinucleating ligand"
Chemical Science, 2014, 5, 2282-2292.
DOI:10.1039/C3SC51541A

2.

Yutaka Hitomi*, Tomoyuki Ekawa, and Masahito Kodera
"Water Proton Relaxivity, Superoxide Dismutase-like Activity, and Cytotoxicity of a Manganese(III) Porphyrin Having Four Poly(ethylene glycol) Tails"
Chemistry Letters, 2014, 43(5), 732-734.
DOI:10.1246/cl.140029

1.

Yutaka Hitomi*, Yuji Iwamoto, and Masahito Kodera
"Electronic Tuning of Nitric Oxide Release from Manganese Nitrosyl Complexes by Visible Light Irradiation: Enhancement of Nitric Oxide Release Efficiency by Nitro-Substituted Quinoline Ligand"
Dalton Transactions, 2014, 43, 2161-2167.
DOI:10.1039/C3DT51719E

2013

4.

Yutaka Hitomi*, Akiko Nomura, Ryosuke Miyachi, Toshiyuki Takeyasu, and Masahito Kodera
"Peptide Conjugates of Organoselenium Compounds with Glutathione Peroxidase-Like Activity"
Peptide Science, 2013, 199-202.

3.

Yutaka Hitomi*, Toshiyuki Takeyasu, and Masahito Kodera
"Iron Complex-Based Fluorescent Probes for Intracellular Hydrogen Peroxide Detection"
Chemical Communications, 2013, 49, 9929-9931.
DOI:10.1039/C3CC44471F

2.

Yutaka Hitomi*, Kazuaki Hiramatsu, Kengo Arakawa, Toshiyuki Takeyasu, Masashi Hata, and Masahito Kodera
"An Iron(III) Tetradentate Monoamido Complex as a Nonheme Iron-Based Peroxidase Mimetic"
Dalton Transactions, 2013, 42 (36), 12878-12882.
DOI:10.1039/C3DT51483H

1.

Yutaka Hitomi*, Kengo Arakawa, and Masahito Kodera
"Electronic Tuning of Iron-Oxo Mediated C-H Activation: Effect of Electron Donating Ligand on Selectivity"
Chemistry - A European Journal, 2013, 19 (43), 14697-14701.
DOI: 10.1002/chem.201302111

2012

7.

Yutaka Hitomi*, Toshiyuki Takeyasu, Shoko Matsuda, Akiko Nomura, Akihiro Kashida, Masanori Hayashi, and Masahito Kodera
"Synthesis and Characterization of Ratiometric Fluorescent Zinc Ion Probe Having Cationic Short Peptide Tail"
Peptide Science, 2012, 297-300.

6.

Yutaka Hitomi*, Akiko Nomura, Shoko Matsuda, Akihiro Kashida, and Masahito Kodera
"Oxidative DNA Cleavage by Synthetic Mononuclear Nonheme Iron Complex Having Cationic Short Peptide Tail for DNA Binding"
Peptide Science, 2012, 279-282.

5.

Yutaka Hitomi*, Toshiyuki Nagai, and Masahito Kodera
"A Silver Complex with an N,S,S-Macrocyclic Ligand Bearing an Anthracene Pendant Arm for Optical Ethylene Monitoring"
Chemical Communications, 2012, 48, 10392-10394, selected as the back cover of the issue.
DOI:10.1039/C2CC35277J

4.

Masahito Kodera*, Yuka Kawahara, Yutaka Hitomi, Takashi Nomura, Takashi Ogura, and Yoshio Kobayashi
"Reversible O-O Bond Scission of Perox-odiiron(III) to High Spin Oxodiiron(IV) in Dioxygen Activation of Diiron Center with a Bis-tpa Dinucleating Ligand as a sMMO Model"
Journal of the American Chemical Society, 2012, 134(32), 13236-13239.
DOI:10.1021/ja306089q

3.

Kazuhisa Kakeya, Aya Nakagawa, Tadashi Mizutani,* Yutaka Hitomi, and Masahito Kodera
"Synthesis, Reactivity, and Spectroscopic Properties of meso-Triaryl-5-oxaporphyrins"
Journal of Organic Chemistry, 2012, 77(15), 6510-6519.
DOI:10.1021/jo3010342

2.

Tsunehiro Tanaka*, Junya Ohyama, Kentaro Teramura, and Yutaka Hitomi
"Formation mechanism of metal nanoparticles studied by XAFS spectroscopy and effective synthesis of small metal nanoparticles"
Catalysis Today, 2012, 183(1), 108-118.
DOI:10.1016/j.cattod.2011.09.003.

1.

Yutaka Hitomi*, Kengo Arakawa, Takuzo Funabiki, and Masahito Kodera
"An Iron(III) Monoamidate Complex Catalyst for Selective Hydroxylation of Alkane C?H Bonds with Hydrogen Peroxide"
Angewandte Chemie International Edition, 2012, 51(14), pp 3448?3452.
DOI: 10.1002/anie.201108933

2011

7.

Yutaka Hitomi*, Toshiyuki Takeyasu, Takuzo Funabiki, and Masahito Kodera
"Detection of Enzymatically Generated Hydrogen Peroxide by Metal-Based Fluorescent Probe"
Analytical Chemistry, 2011, 83 (24), pp 9213?9216.
DOI: 10.1021/ac202534g

6.

Shinya Furukawa, Yutaka Hitomi*, Tetsuya Shishido, Kentaro Teramura, and Tsunehiro Tanaka
"π Back-Bonding of Iron(II) Complexes Supported by Tris(pyrid-2-ylmethyl)amine and its Nitro-Substituted Derivatives"
Journal of Physical Chemistry A, 2011, 115(46), 13589-95.
DOI: 10.1021/jp2069539

5.

Yutaka Hitomi*, Akihiro Kashida, Akiko Nomura, Masanori Hayashi, and Masahito Kodera
"Synthesis and characterization of zinc chelator conjugated with cationic peptide"
Peptide Science, 2011, 319-321.

4.

Shinya Furukawa, Yutaka Hitomi*, Tetsuya Shishido and Tsunehiro Tanaka
"Efficient aerobic oxidation of hydrocarbons promoted by high-spin nonheme Fe(II) complexes without any reductant"
Inorganica Chimica Acta, 2011, 378(1), 19-23.
DOI: 10.1016/j.ica.2011.08.004

3.

Junya Ohyama, Kentaro Teramura, Yasuhiro Higuchi, Tetsuya Shishido, Yutaka Hitomi*, Kazuki Aoki, Takuzo Funabiki, Masahito Kodera, Kazuo Kato, Hajime Tanida, Tomoya Uruga, and Tsunehiro Tanaka*
"An in situ quick XAFS spectroscopy study on the formation mechanism of small gold nanoparticles supported by porphyrin-cored tetradentate passivants"
Physical Chemistry Chemical Physics, 2011, 13, 11128-11135.
DOI: 10.1039/c1cp20231f

2.

Naoki Nakatani, Yutaka Hitomi, Shigeyoshi Sakaki*
"Multi-State CASPT2 Study of Native Iron(III)-dependent Catechol Dioxygenase and Its Functional Models: Electronic Structure and Ligand-to-Metal Charge-Transfer Excitation"
Journal of Physical Chemistry B, 2011, 115(16), pp 4781-4789.
DOI: 10.1021/jp110045f

1.

Junya Ohyama, Kentaro Teramura, Tetsuya Shishido, Yutaka Hitomi, Kazuo Kato, Hajime Tanida, Tomoya Uruga, Tsunehiro Tanaka
"In situ Au L3 and L2 Edge XANES Spectral Analysis during Growth of Thiol Protected Gold Nanoparticles for the Study on Particle Size Dependent Electronic Properties"
Chemical Physics Letters, 2011, 507(1-3), pp 105-110.
DOI: 10.1016/j.cplett.2011.03.020

2010

5.

Yuuji Kajita, Yoshimitsu Tachi, Yutaka Hitomi, Tomoyuki Nakagawa, Yoshihisa Kishima, Masahito Kodera
"TRIS(2-PICOLINYL)METHANE AND ITS COPPER(I) COMPLEX"
Inorganic Syntheses, 2010, Vol. 35, 74-77, Thomas Rauchfuss (Editor-in-Chief), Inorganic Syntheses, Inc.

4.

Junya Ohyama, Kentaro Teramura, Yasuhiro Higuchi, Tetsuya Shishido, Yutaka Hitomi, Kazuo Kato, Hajime Tanida, Tomoya Uruga, and Tsunehiro Tanaka
"In-situ Observation of Nucleation and Growth Process of Gold Nanoparticles by Quick XAFS Spectroscopy"
ChemPhysChem, 2010, 12 (1), 128-131.
DOI: 10.1002/cphc.201000731

3.

Tetsuya Shishido, Toru Kawaguchi, Tomohito Iwashige, Kentaro Teramura, Yutaka Hitomi, and Tsunehiro Tanaka
"Synthesis and catalytic performance of organic-inorganic hybrid mesoporous material having basic nanospace"
Catalysis Letters, 2010, 140, 3-4, 121-126.
DOI: 10.1007/s10562-010-0456-3

2.

Yutaka Hitomi*, Junya Ohyama, Yasuhiro Higuchi, Kazuki Aoki, Tetsuya Shishido, Takuzo Funabiki, Masashito Kodera, Tsunehiro Tanaka
"Efficient Capping of Growing Gold Nanoparticles by Porphyrin Having Two Disulfide Straps over One Face"
Bulletin of the Chemical Society of Japan, 2010, 83(11), 1392-1396.
DOI: 10.1246/bcsj.20100160

1.

Yutaka Hitomi*, Junya Ohyama, Minori Takegoshi, Akira Ando, Takuzo Funabiki, Masashito Kodera, Tsunehiro Tanaka
"Fast Guest Exchange of a 1:1 Zinc Porphyrin-Amine Host-Guest Complex via a Six-Coordinated Zinc Porphyrin"
Bulletin of the Chemical Society of Japan, 2010, 83(8), 950-952.
DOI: 10.1246/bcsj.20100007

2009

3.

Tetsuya Shishido, Toshiaki Miyatake, Kentaro Teramura, Yutaka Hitomi, Hiromi Yamashita, Tsunehiro Tanaka
"Mechanism of photooxidation of alcohol over Nb2O5"
Journal of Physical Chemistry C, 2009, 113(43), 18713-18718.

2.

Junya Ohyama, Yutaka Hitomi, Yasuhiro Higuchi, Tsunehiro Tanaka
"Size-controlled synthesis of gold nanoparticles by porphyrin with four sulfur atoms"
Topics in Catalysis, 2009, 52(6-7), 852-859.

1.

Wadih Ghattas, Zeinab Serhan, Nadia El Bakkali-Taheri, Marius Reglier, Masahito Kodera, Yutaka Hitomi, A. Jalila Simaan
"Synthesis and Characterization of a Binuclear Iron(III) Complex Bridged by 1-Aminocyclopropane-1-carboxylic Acid. Ethylene Production in the Presence of Hydrogen Peroxide"
Inorganic Chemistry, 2009, 48(9), 3910-3912.

2008

4.

Junya Ohyama, Yutaka Hitomi,* Yasuhiro Higuchi, Masashi Shinagawa, Hidefumi Mukai, Masahito Kodera, Kentaro Teramura, Tetsuya Shishido, Tsunehiro Tanaka
"One-phase synthesis of small gold nanoparticles coated by a horizontal porphyrin monolayer"
Chemical Communications, 2008, 6300-6302.
DOI: 10.1039/B815100H

3.

Adam T. Fiedler, Xiaopeng Shan, Mark P. Mehn, Jozsef Kaizer, Stephane Torelli, Jonathan R. Frisch, Masahito Kodera, Lawrence Que Jr.*
"Spectroscopic and computational studies of (mu-oxo)(mu-1,2-peroxo)diiron(III) complexes of relevance to nonheme diiron oxygenase intermediates"
Journal of Physical Chemistry, 2008, 112 (50), pp 13037-13044.
DOI: 10.1021/jp8038225

2.

Yutaka Hitomi*, Shinya Furukawa, Masakazu Higuchi, Tetsuya Shishido, Tsunehiro Tanaka
"Alkane hydroxylation catalyzed by a series of mononuclear nonheme iron complexes containing 4-nitropyridine ligands"
Journal of Molecular Catalysis A: Chemical (2008), 288(1-2), 83-86.
DOI: 10.1016/j.molcata.2008.03.021

1.

Wadih Ghattas, Michel Giorgi, Yasmina Mekmouche, Tsunehiro Tanaka, Antal Rockenbauer, Marius Reglier, Yutaka Hitomi*, A. Jalila Simaan*
"Identification of a copper(I) intermediate in the conversion of 1-aminocyclopropane carboxylic acid (ACC) into ethylene by Cu(II)-ACC complexes and hydrogen peroxide"
Inorganic Chemistry (2008), 47(11), 4627-4638.
DOI: 10.1021/ic702303g

Other publications


2014

武安俊幸,人見 穣,小寺政人
"細胞内過酸化水素を可視化するプローブ分子の開発”
”Development of Molecular Probes for Intracellular Hydrogen Peroxide Imaging"
同志社大学理工学研究報告, submitted.
The Science and Engineering Review of Doshisha University, 2014.

2013

人見 穣・小寺 政人
"自然に学ぶ選択酸化触媒"
月刊バイオインダストリー, シーエムシー出版, 2013年3月号 リンク

2012

荒川健吾・人見 穣・小寺 政人
"高選択的C-H活性化触媒の開発-非ヘム高原子価鉄オキソ種の化学"
化学, 化学同人, Vol. 67, No.9, 72-73 (2012) リンク

2011

人見 穣, 荒川健吾,矢野順也,畑征志,齋藤沙知,小寺政人
"金属酵素作用機序に触発された精密設計金属錯体触媒の開発”
”Development of Metal-complex Catalysts Inspired by the Action Mechanism of Metalloenzymes"
同志社大学理工学研究報告
The Science and Engineering Review of Doshisha University, 2011, 52(3), 171-176.


2009

小寺 政人
"金属タンパク質の機能を再現する高機能性多核金属錯体の開発"
化学工業-特集/次世代材料を創成する錯体化学, 化学工業社, Vol.60, No.8, 58-64 (2009) リンク


バナースペース

Department of Applied Chemistry, Graduate School of Science and Engineering
Doshisha University

1-3 Tatara Miyakodani, Kyotanabe, Kyoto 610-0394, Japan